You're probably using YMSGv102 which doesn't allow photoshare.
Sign out of Yahoo! Messenger;
Go to the YTK Control Panel, Security (spider web icon), "Auto-Reconnect Protocol Version" change it to 15 if you're still using Yahoo! Messenger 8.1
Alternatively you can sign out of Yahoo! Messenger and uncheck "Auto-Reconnect".
Also you may want to look at this since it seems you're having a lot of difficulties;
http://www.ytk.smfnew.com/index.php?topic=148.0
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